Bifunctional cross-conjugated luminescent phosphines and phosphine derivatives: phospha-cruciforms.

نویسندگان

  • Anshuman Mangalum
  • Rhett C Smith
چکیده

Cross-conjugated bifunctional species including a phosphine, phosphine oxide, phosphine sulfide, phosphonium salt, phosphorus ylide and a gold(I) phosphine complex have been prepared. The photophysical characteristics of the series of compounds have been determined experimentally and are discussed/compared with simpler analogues lacking cross-conjugated branches and rationalized on the basis of DFT calculations.

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عنوان ژورنال:
  • Dalton transactions

دوره 39 21  شماره 

صفحات  -

تاریخ انتشار 2010